CAS:18388-03-9|2-​(Chloromethyl)​allyl-​trimethylsilane

Catalogue Number:C371430
Chemical Name:2-​(Chloromethyl)​allyl-​trimethylsilane
Synonyms:2-Chloromethyl-3-trimethylsilyl-1-propene; 2-Chloromethyl-3-trimethylsilylpropene
CAS Number:18388-03-9
Molecular Formula:C₇H₁₅ClSi
Appearance:Clear Colourless Oil
Molecular Weight:162.73
Storage:4°C, Inert atmosphere, Light sensitive
Solubility:Chloroform, Methanol (Slightly)
Stability
Moisture Sensitive
Category:Building Blocks; Miscellaneous;
Applications:2-​(Chloromethyl)​allyl-​trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-​(Chloromethyl)​allyl-​trimethylsilane was used in catalytic Sakurai reaction of a,​b-​enones.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References:Kopecky, D., et al.: J. Am. Chem. Soc., 123, 8420 (2001).
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