CAS:930601-66-4|(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate

Catalogue Number:A164155
Chemical Name:(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate
Synonyms:Alkene Zipper Catalyst
CAS Number:930601-66-4
Molecular Formula:C₂₁H₃₅N₃PRu⁺ • PF₆⁻
Molecular Weight:606.53
Category:Building Blocks;
Applications:(Acetonitrile)[4-tert-butyl-2-(diisopropylphosphino)-1-methyl-1H-imidazole-κN,κP](η5-cyclopentadienyl)ruthenium(1+) hexafluorophosphate, is an Alkene Zipper Catalyst, used in selective transformation of a large variety of ω-alkenyl cyclopropylcarbinols into stereodefined unconjugated (E)-acyclic aldehydes .
References:Bruffaerts, J., Vasseur, A., & Marek, I. (2018). Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol. Advanced Synthesis & Catalysis, 360(7), 1389–1396.
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