Catalogue Number:B053100
Chemical Name:Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate
Synonyms:Ruthenium(2+), tris(2,2′-bipyridine-N,N’)-, (OC-6-11)-, bis[hexafluorophosphate(1-)];Ruthenium(2+), tris(2,2′-bipyridine-κN1,κN1′)-, (OC-6-11)-, bis[hexafluorophosphate(1-)] (9CI); Phosphate(1-), hexafluoro-, (OC-6-11)-tris(2,2′-bipyridine-N,N’)ruthenium(2+) (2:1); Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate(1-)); Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate); Tris(2,2′-bipyridine)ruthenium hexafluorophosphate; Tris(2,2′-bipyridine)ruthenium(2+) bis(hexafluorophosphate); Tris(2,2′-bipyridine)ruthenium(2+) bis[hexafluorophosphate(1-)]; Ruthenium(2+), tris(2,2′-bipyridine-κN1,κN1′)-, (OC-6-11)-, hexafluorophosphate(1-) (1:2)
CAS Number:60804-74-2
Molecular Formula:C₃₀H₂₄N₆Ru • 2(F₆P⁻⁾
Appearance:Orange to Brown Solid
Molecular Weight:569.62 + (144.96)
Storage:4°C
Solubility:DMSO (Slightly), Methanol (Slightly)
Category:Building Blocks; Catalyst;
Applications:Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate has been used to catalyze radical silylation of biarylhydrosilanes to give dibenzosiloles via dehydrogenative cyclization.
References:Yang, C.; et al.: Advanced Synthesis & Catalysis, 360, 3049 (2018).
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CAS:60804-74-2|Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate
