CAS:1011257-42-3|Copper (I) Diphenylphosphinate

Catalogue Number:C685395
Chemical Name:Copper (I) Diphenylphosphinate
Synonyms:P,P-Diphenyl Copper Phosphinic Acid Salt
CAS Number:1011257-42-3
Alternate CAS #
1707-03-5
Molecular Formula:C₁₂H₁₀CuO₂P
Appearance:Pale Green to Light Green Solid
Melting Point:>160°C (dec.)
Molecular Weight:280.73
Storage:-20°C, Hygroscopic
Solubility:Aqueous Acid (Slightly)
Stability
Hygroscopic, Moisture Sensitive
Category:Building Blocks; Catalyst;
Applications:Copper (I) Diphenylphosphinate functions as a catalyst in the enantioselective synthesis of (-)-viridin, (-)-viridiol (a fungal steroid with phytotoxic activity) and in the stereoselective synthesis of C1-C16 fragment of goniodomin A.
References:Del Bel, M., et al.: J. Am. Chem. Soc., 139, 6819 (2017); Nakajima, M., et al.: Bull. Chem. Soc. Jpn, 85, 948 (2012)
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