CAS:10548-46-6|1,6-Anhydro-2,3,4-tri-O-benzyl-b-D-glucopyranose

Catalogue Number:A658750
Chemical Name:1,6-Anhydro-2,3,4-tri-O-benzyl-b-D-glucopyranose
Synonyms:1,6-Anhydro-2,3,4-tris-O-(phenylmethyl)-β-D-glucopyranose; Tri-O-benzyllevoglucosan;
CAS Number:10548-46-6
Molecular Formula:C₂₇H₂₈O₅
Appearance:Off-White Solid
Melting Point:81-84°C
Molecular Weight:432.51
Storage:-20°C
Solubility:Chloroform, Ethyl Acetate
Category:Building Blocks; Carbohydrates and Oligosaccharides;
Applications:1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.
References:Fraser-Reid, B., et al. J. Am. Chem. Soc. 106, 731 (1984); Edwards, M.P., et al. J. Org. Chem. 49, 3503 (1984); Kelly, A.G., and Roberts, J.S. J. Chem. Soc., Chem. Commun. 228, (1980); Ogawa, T., et al. Carbohydr. Res. 57, C31 (1977); Isobe, M., et al. Tetrahedron Lett. 28, 6485 (1987); Fresnos, J.N. and Swenton, J.S. , J. Chem. Soc., Chem. Commun. 658, (1985); Kochetkov, N.K. et al., Tetrahedron Lett. 22, 4315, 4319 (1981); Georges, M. et al., Carbohydr. Res. 130, 115 (1984); Paulsen, et al., Chem. Ber. 114, 322 (1981).
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