CAS:192139-90-5|[(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride]

Catalogue Number:C989475
Chemical Name:[(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride]
Synonyms:[RuCl(TsDPEN)(η-6-cymene)]; [((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)(η6-p-cymene)ruthenium; , [S-(R*,R*)]-[N-[2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium; [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium
CAS Number:192139-90-5
Molecular Formula:C₃₁H₃₅ClN₂O₂RuS
Appearance:Orange Solid
Molecular Weight:636.21
Solubility:Chloroform, DCM, Ethyl Acetate
Category:Research Tools; Chiral Molecules; Miscellaneous;
Applications:[(η-6-Cymene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaminato]ruthenium] chloride] is an catalyst used for enantioselective hydrogenation of quinolines, N-Alky Ketimines and antitumor, antiproliferative derivatives of natural products isolated from bacteria.
References:Bligh, C.M., et al.: J. Org. Chem., 79, 328 (2014); Brownell, K.R., et la.: J. Am. Chem. Soc., 135, 14299 (2013);
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